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In 2007 Zimmermann appeared on the cover of V and in the first ever television commercial by Gucci for its new fragrance, Gucci by Gucci, directed by David Lynch.

The year starts of with none other than Adriana Lima nude top to bottom followed by the beautiful Natalia Vodianova baring her breasts in bed and Karen Elson seated topless.

The May 2009 issue of American Vogue featured her as one of the faces of the season, alongside Liya Kebede, Lara Stone, Natasha Poly, Caroline Trentini, Jourdan Dunn, Natalia Vodianova, Anna Jagodzinska, and Isabeli Fontana.

Raquel reports that she practices the Transcendental Meditation technique.

As of April 2011 she was, because of her long run on the Top 100, ranked 14 on the Top Model Icons of All Time list.

Zimmermann was discovered by a scouting agency in Porto Alegre, Brazil at the age of 14 and made her way to Japan and on to Paris.